A sealed flask at constant temperature initially holds only N₂O₄ gas, which reacts by N₂O₄(g) ⇌ 2NO₂(g). The graph shows the concentrations over 80 s. Which statement about the system at 60 s is supported by the graph?
Question 2
Cell potentials of metals A, B and C, each joined to a standard copper half-cell
Metal half-cell
Measured cell potential (V)
Positive electrode
A in 1 mol L⁻¹ A²⁺(aq)
1.10
copper
B in 1 mol L⁻¹ B²⁺(aq)
0.20
metal B
C in 1 mol L⁻¹ C²⁺(aq)
0.47
copper
Students in a Townsville laboratory join half-cells of three unknown metals, A, B and C, each to a standard copper half-cell, E°(Cu²⁺/Cu) = +0.34 V, and record the results in the table. Which two of the metal half-cells would make the cell with the largest E°cell, and what is that value?
Question 3
In a dimly lit laboratory, a student shakes hexane and hex-1-ene separately with orange bromine water at room temperature. Which observation is expected?
Question 4
Equilibrium percentage of ammonia at four temperatures and three pressures
Temperature (°C)
10 000 kPa
20 000 kPa
30 000 kPa
350
30
45
54
400
25
36
46
450
16
27
35
500
10
18
26
The table gives the percentage of ammonia at equilibrium for N₂(g) + 3H₂(g) ⇌ 2NH₃(g) under different conditions. An engineer needs at least 30% ammonia at equilibrium and, of the conditions that achieve this, wants the fastest rate. Which conditions in the table should she choose?